Time evolution of a rifted continental arc: Integrated ID-TIMS and LA-ICPMS study of magmatic zircons from the Eastern Srednogorie, Bulgaria

Abstract

Eastern Srednogorie in Bulgaria is the widest segment of an extensive magmatic arc that formed by convergence of Africa and Europe during Mesozoic to Tertiary times. Northward subduction of the Tethys Ocean beneath Europe in the Late Cretaceous gave rise to a broad range of basaltic to more evolved magmas with locally associated Cu–Au mineralization along this arc. We used U–Pb geochronology of single zircons to constrain the temporal evolution of the Upper Cretaceous magmatism and the age of basement rocks through which the magmas were emplaced in this arc segment. High precision isotope dilution-thermal ionization mass spectrometry (ID-TIMS) was combined with laser ablation-inductively coupled plasma mass spectrometry (LA–ICPMS) for spatial resolution within single zircon grains.Three tectono-magmatic regions are distinguished from north to south within Eastern Srednogorie: East Balkan, Yambol–Burgas and Strandzha. Late Cretaceous magmatic activity started at ~92Ma in the northernmost East Balkan region, based on stratigraphic evidence and limited geochronology, with the emplacement of minor shallow intrusions and volcanic rocks onto pre-Cretaceous basement. In the southernmost Strandzha region, magmatism was initiated at ~86Ma with emplacement of gabbroic to dioritic intrusions and related dikes into metamorphic basement rocks that have previously been overprinted by Jurassic–Lower Cretaceous metamorphism. The Yambol–Burgas region is an extensional basin between the East Balkan and the Strandzha regions, which broadens and deepens toward the Black Sea further east and is filled with a thick pile of marine sediments and submarine extrusive volcanic rocks accompanied by coeval intrusions. This dominantly mafic magmatism in the intermediate Yambol–Burgas region commenced at ~81Ma and produced large volumes of potassium-rich magma until ~78Ma. These shoshonitic to ultrapotassic basaltic to intermediate magmas formed by differentiation of ankaramitic (high Ca) parental melts, produced from partial remelting of amphibole clinopyroxenites upon interaction with subduction-modified mantle wedge melts, according to earlier petrological studies. This peak of dominantly extrusive activity in the Yambol–Burgas region extended into the Strandzha region further south, in the form of numerous tholeiitic, calc-alkaline and high-K intrusions emplaced in the same time period between 81 and 78Ma.Granitic rocks from exposed basement of Eastern Srednogorie zone are dated as Permian/Carboniferous (~275–300Ma). Zircons with similar ages occur in Upper Cretaceous rocks from the East Balkan and Strandzha regions, indicating local incorporation as xenocrysts. In contrast, magmatic rocks from the intermediate Yambol–Burgas region contain mostly Ordovician (~460Ma) or older inherited zircons, suggesting a either a different basement history or, more likely, a different level of magma storage and crustal assimilation.Integrating these geochronological results with a synthesis of the regional geology, we propose a two-stage geodynamic evolution for the Eastern Srednogorie segment of the Tethyan arc. The earlier stage of normal arc magmatism was driven by a southward slab retreat, which formed the ~92Ma calc-alkaline to high-K shallow intrusions and volcanics in the north (East Balkan), 87–86Ma old tholeiitic and calc-alkaline intrusions in the south (Strandzha), and the voluminous 81–78Ma old gabbroic to granitic intrusions with predominantly calc-alkaline to high-K composition throughout the Strandzha region. This stage continued westward into the Central Srednogorie zone, where the southward younging of calc-alkaline magmatism correlates well with an increased input of primitive mantle melts, indicating asthenospheric incursion into a widening mantle wedge as a result of slab roll-back. The second stage proceeded in the Eastern Srednogorie zone only, where more extreme extension associated with the opening of the Black Sea back-arc basin led to the formation of an intra-arc rift in the Yambol–Burgas region, which now separates the East Balkan region from the Strandzha region. In this extensional environment, crustal thinning lead to decompression and increased heat flow, facilitating large-scale melting of lower crustal rocks and the formation of 81–78Ma magmas. The unusual calcic composition of the parent magmas, their isotopic character and distinct xenocrystic population are consistent with a component of re-melting of hydrous lower-crustal cumulates, which probably formed in part during the first stage of the evolving arc.