Abstract
Soil water exerts a strong influence on the transfer and storage of solutes, heat, air, and even water itself, within the soil profile. Soil water also dominates the mass and energy balance of the soil–atmosphere interface. Over the last decade or so, the development and continuing refinement of the time-domain reflectometry (TDR) technique for in situ, nondestructive measurement of water, ionic solutes and air has revolutionized the study and management of the transfer and storage of mass and energy within the soil profile. TDR-measured water content has been applied successfully to water balance studies ranging from the km scales of small watersheds to the mm scale of the root–soil interface. TDR-measured ionic solute status, which applies to the same sample volume as the water content measurement, has been used successfully on soil column, field plot and whole field scales for in situ determination of solute transport parameters, such as pore water velocity and dispersivity. TDR-measurement of air-filled porosity in space and time has given new insights into the mechanisms controlling aeration and gaseous exchange in the crop root zone. The combined water content – solute mass measurement capability of TDR has made this technique a very powerful tool for characterizing solute leaching characteristics, as well as for evaluating solute transport theories and solute transport models. The portability of TDR instrumentation coupled with the simplicity and flexibility of TDR soil probes has allowed the separation of water and solute content measurement error from soil variability, resulting in the capability for determining the mechanisms behind the spatial and temporal variability in field-based soil water content distributions and solute leaching patterns. The usefulness and power of the TDR technique for characterizing mass and energy in soil is increasing rapidly through continuing improvements in operating range, probe design, multiplexing and automated data collection.
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