Abstract

In this work, we presented a one-pot hydrothermal approach to produce Bi2MoO6/BiOCl heterojunction in the presence of dichloromethane (CH2Cl2) as the source of chloridion (Cl−) through alcoholysis. The gradual production of Cl− can elaborately manipulate the composites’ morphology leading to the time-controlled assembly of BiOCl nanosheets onto Bi2MoO6 surface; a pronounced Bi2MoO6/BiOCl heterojunction was observed with prolonged reaction time. The Bi2MoO6/BiOCl composites obtained at 6 h exhibited the highest specific capacitance of 651 F g−1 at 1 A g−1, meanwhile, the specific capacitance could be retained at ∼85% after 5000 cycles at a current of 4 A g−1, rendering this Bi2MoO6/BiOCl heterojunction as a promising electrode material for supercapacitors.

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