Time dependent correlations of entangled states with nondegenerate branches and possible experimental realization using singlet fission.

Abstract

The spin-entangled exciton states produced by singlet fission provide an experimental route to generate entangled states with nondegenerate branches. Nondegenerate entangled pair states possess an internal "clock" that leads to quantum beating in various detected quantities. The implications of this internal clock for Bell's inequality measurements and correlated particle detection are analyzed using two- and three-state spin models. In a Bell's inequality experiment, we find that the choice of detection times can determine whether quantum or classical correlations are observed. The conditions under which the detection events could be time- or spacelike separated are analyzed in order to clarify how the temporal evolution of one particle can influence the time-dependent detection probability of the other. Possible routes to the detection of individual correlated triplet excitons are discussed, emphasizing both physical questions concerning the separation and propagation of triplet excitons over macroscopic distances and experimental challenges concerning decoherence, detection, and interpretation of the signals. We argue that spin-entangled triplet exciton states produced by singlet fission could provide a new way to probe entangled state detection and collapse, complementing schemes based on polarization-entangled photon states.