Abstract
We present experimental measurements of time-dependent photoelectron spectra observed in thermionic emission of small carbon cluster anions and C 60 fullerenes. The combination of photoelectron velocity-map imaging with time-gated detection allowed to resolve delayed electron emission at different stages of the emission process. This unique capability allows us to analyze pure thermionic energy spectra under well-defined conditions. Experimental spectra are analyzed within the framework of the detailed balance theory.
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