Abstract
Abstract We were the first to investigate the properties of the archaeal 36-membered macrocyclic diether phospholipid 1a in comparison with the corresponding acyclic counterpart 2a. Results from thermal analyses and monolayer studies indicated that the 36-membered macrocyclic diether lipid can aggregate to more tightly packed structures than the acyclic congener due to less motional freedom at the alkyl chain region.
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