Tidal variability of polycyclic aromatic hydrocarbons and organophosphate esters in the coastal seawater of Dalian, China

Abstract

We investigated the tidal variability of polycyclic aromatic hydrocarbons (PAHs) and organophosphate esters (OPEs) in water dissolved phase from a coastal area of Dalian, China, as well as their air-water exchange trends. The concentrations of PAHs and OPEs in water were in the range of 50.5–74.7 ng/L and 21.6–61.5 ng/L, respectively. Phenanthrene (PHE) was the dominant congener followed by fluorene (FLU) for PAHs, while tris(2-chloroisopropyl) phosphate (TCIPP) and tris(2-chloroethyl) phosphate (TCEP) dominated for OPEs. PAHs in coastal water showed a tidal variability, but not for OPEs, which may due to the influence of occasional wastewater discharges of OPEs. The source apportionments using principle component analysis and positive matrix factorization suggested that PAHs in the coastal water mainly came from oil spill from ships, coal combustion, and petroleum combustion, while OPEs were derived from diverse sources. The fugacity fractions (ff) suggested that ACY, ACE, FLU, PHE, TCEP, and TPHP volatilized from water into air, while TNBP, TCIPP, and TDCIPP deposited from air into water, and FLA, PYR, BaA, CHR, and EHDPP reached equilibrium. The ff values varied slightly with tidal circle, but the variations were not enough to alter the air-water exchange directions of those compounds. Although the influences of tide on the air-water exchange of PAHs and OPEs were limited, tide still played an important role on the transports and diffusions of those chemicals in the coastal water, which requires further studies.