Abstract
The Ti 2 p - and Ti 3 p -resonant photoemission studies of Ti 2 O 3 were carried out as well as O 1 s -resonant photoemission. The Ti 3 d band has a broad band width of about 3 eV, but the strong resonance enhancement was observed at Ti 3 d band just below the Fermi level on the Ti 2 p resonance. The enhancement of the doublet Ti 3 p main line was observed mainly at the higher binding energy. The resonant enhancements of the satellite structures in the Ti 3 d and Ti 3 p band regions were also found. The resonance spectra were analyzed by the cluster model calculation with large hybridization energy, where the satellite was elucidated by the charge transfer satellite.
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