Abstract

Abstract1‐Chlor‐3.4‐di O‐acetyl‐2‐desoxy‐D‐xylopyranose (2) reagiert sowohl mit 2.4‐Bis‐O‐trimethyl‐silyl‐thymin (1) in Gegenwart von AgClO4 oder HgO/HgBr2 als auch mit Monoquecksilber‐thymin (3) in Dimethylformamid zu einem Gemisch acetylierter Nucleoside, aus dem nach Entacetylierung durch Säulenchromatographie 1‐[2‐Desoxy‐α‐D‐xylopyranosyl]‐thymin (α‐6) und sein β‐Anomeres (β‐6) isoliert werden können.

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