Abstract
A facile chemical template method named supramolecular assembly and deaggregation was used to prepare three-dimensional (3D) hierarchical 2,2,4,4,6,6-hexanitrostilbene (HNS) crystalline clusters. Dioxane was used as the guest molecule for guidance in the assembly process. The 3D hierarchical HNS crystalline clusters possess multiple distributions of particle size and pore size, which results in significantly different safety performance compared to raw HNS. Furthermore, the formation mechanism of these unique structures was proposed based on the experimental results. This work provides a convenient method to prepare hierarchical energetic materials with porous micro/nano structures and other hierarchical functional materials such as catalysts, adsorbents, micro reactors and sensors.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
