Abstract
Abstract Three variants of novel cobalt(II) complex with deprotonated mefenamic acid (mef) and N,N′-donor ligand neocuproine (neo) are described, namely; two differently colored and shaped crystal polymorphs of complex [Co(mef)2(neo)] (1a and 1b) and a pyridine solvate [Co(mef)2(neo)]·py (2). The complexes have been characterized by infrared and UV-VIS spectroscopy, elemental analysis and single-crystal X-ray structure analysis. Although the complexes 1a, 1b and 2 crystallize in different crystal systems and space groups and differ in shapes of coordination polyhedra, the crystal structures of all three complexes contain analogous neutral units with Co(II) atom hexacoordinated by two chelate bonded mefenamato ligands and one chelate bonded neocuproine ligand, yielding CoN2O4 chromophore. The main structural difference between 1a, 1b and 2 is the conformation of the coordinated mef ligands, which affects the crystal packing of the complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für Kristallographie - Crystalline Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
