Abstract

HighlightsThree-phase heterojunction can adjust the ∆G of H/O-intermediates to boost catalytic activity.At ± 1000 mA cm−2, Ni/MoO2@CN exhibits low hydrogen/oxygen evolution reaction overpotentials (267/420 mV).Ni/MoO2@CN used as bifunctional electrodes can work at 1000 mA cm−2 for 330 h in 6.0 M KOH + 60 °C condition.

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