Three-phase froth stability in hematite flotation using DDA as a collector

Abstract

The effect of hematite and quartz with different particle sizes on the three-phase froth stability using dodecylamine (DDA) as a collector was investigated, and the mechanism of how quartz improves froth stability was explored. Microflotation experiment, three-phase froth stability experiment, froth morphology photography, pulp viscosity measurement, contact angle measurement, zeta potential measurement, time-of-flight secondary ion mass spectrometry analysis, and molecular dynamics simulation were conducted in this investigation. Results showed that flotation performance and froth stability were obviously different for minerals with different particle sizes. The froth half-life was remarkably higher in the presence of quartz particles compared with hematite particles, forming stickier froth, especially for quartz particle sizes below −18 μm. Fine quartz was found to be a key factor in improving the froth stability in hematite flotation using DDA as a collector. The high pulp viscosity, damping coefficient, and maximum capillary pressure resulting from quartz with low density, small size, and high concentration hindered liquid drainage and reduced the desorption probability of particles from the bubble surface, thereby preventing the coalescence of two adjacent bubbles. DDA was found to be more readily adsorbed on the quartz surface, leading to a higher adsorption capacity, better hydrophobicity, and increased distribution of counter ions at the interface. This condition reinforced the mutual repulsion force between liquid film surfaces and prevented further thinning of the liquid film, ultimately strengthening froth stability.