Abstract
Three novel lanthanide polymers, [Ln(III)(L)3EtOH]n (Ln=Tb(1), Ho(2), Er(3), HL=2,3,5-trichlorobenzoic acid), have been solvothermal synthesized and characterized by single-crystal X-ray diffraction, infrared spectroscopy and element analyses. The three polymers crystallize in triclinic space group P-1. The Ln(III) ions are in turn bridged by double and quadruple carboxylate of L− ligands to form one-dimensional (1D) chains. Magnetic studies reveal that polymer 1 demonstrates dominant ferromagnetic behavior, polymer 2 shows antiferromagnetic behavior, and polymer 3 present spin-canting behavior.
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