Abstract
Three isostructural compounds [M(DPFE)(bpda)(H2O)2]n [M=Co(1), Mn(2), Cd(3)] have been synthesized hydrothermally and structurally characterized, where DPFE=2,7-di(pyridin-4-yl)-9H-fluorene and H2bpda=biphenyl-3,4′-dicarboxylic acid. Compounds 1–3 show a unique 2D structure where exists two sets of chains toward two different directions. The solid-state UV–vis absorption spectra of 1–2 and the fluorescence spectrum of 3 are discussed in detail. In addition, compound 3 exhibits relatively high selective ability to detect Ag+ ion in aqueous media.
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