Abstract
Three high-energy salts (3, 4 and 5) based on oxy-bridged bis(gem-dinitro) furazan with potassium and nitrogen-rich cations were reported. Their structures were fully characterized and confirmed by NMR (1H, 13C), IR spectroscopy, elemental analysis and single crystal X-ray diffraction. The thermal decomposition behaviors were studied by DSC and TG methods. And, the decomposition process of 5 was studied by the thermolysis in-situ rapid-scan FTIR. The non-isothermal kinetics parameters were obtained by Kissinger’s and Ozawa’s methods, respectively. The activation entropy (ΔS≠), activation enthalpy (ΔH≠), activation Gibbs free energy (ΔG≠) and the critical temperature of thermal explosion were calculated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
