Three-Dimensional Yttrium Oxalates Possessing Large Channels

Abstract

Two new open-framework yttrium oxalates have been prepared, for the first time, employing hydrothermal methods in the presence of organic amines. The crystal data for these oxalates are as follows: I, [C6N2H16]0.5[Y(H2O)(C2O4)2]·2H2O, triclinic, space group P(−1) (no. 2), a = 8.229(3), b = 9.739(1), c = 9.754(3) A, α = 60.74(1), β = 72.36(1), γ = 84.67(1)°, V = 648.5(1) A3, Z = 2, M = 377.1, Dcalc = 1.931 g cm-3, μ = 4.554 mm-1, Mo Kα, R1 = 0.054, wR2 = 0.13; II, [C5N2H12][Y(C2O4)2], monoclinic, space group Cc (no. 9), a = 11.552(1), b = 17.168(1), c = 8.719(1) A, β = 130.64(1)°, V = 1312.1(1) A3, Z = 2, M = 365.1, Dcalc = 1.848 g cm-3, μ = 4.48 mm-1, Mo Kα, R1 = 0.023, wR2 = 0.057. The Y atom is 9-coordinated in I, forming a D3h triply capped trigonal prism, and 8-coordinated in II, forming a square antiprism. The three-dimensional framework structures of I and II are built up by in-plane linkages between the Y and the oxalate moieties, forming layers with 12-membered honeycomb-like apertures, pillared ...