Abstract
The theoretical formulation of linear and nonlinear molecular spectroscopies applied to isotropic samples (e.g., liquid or gas solutions) goes through a fundamental step known as the rotational averaging of Cartesian tensors. Rotational averaging of Cartesian tensors is a mathematical procedure from which the expressions for the rotationally invariant observables (e.g., rates or intensities), associated with a given spectroscopic process, can be found. In this work, the mathematical/computational procedure for finding the rotational averages of Cartesian tensors of any rank n, which is based on the use of the fundamental isotropic Cartesian tensors (FICTs), is discussed. Moreover, for the first time, a heuristic computational method for finding a set of linearly independent FICTs is proposed. The procedure has been tested for 2 ≤ n ≤ 12, where most of the linear and nonlinear molecular spectroscopies apply (e.g., one-photon and multiphoton absorption, emission, electronic circular dichroism, Raman optical activity, coherent and incoherent mth-harmonic generation, etc.). Finally, it is shown how this computational procedure can be extended for n > 12.
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