Three-Dimensional Polymeric Thallium(I) Morpholinedithiocarbamate [Tl2{S2CN(CH2)4O}2] n and Its Capability of Binding Gold(III) from Solutions: Chemisorption Synthesis of a Heteronuclear Gold(III)–Thallium(III) Complex of the Ionic Type, ([Au{S2CN(CH2)4O}2][TlCl4]) n , the Role of Secondary Interactions Tl…O, Tl…S, and Au…S in the Supramolecular Self-Organization, 13C MAS NMR, and Thermal Behavior

O A Bredyuk,O N Antzutkin,A V Ivanov,V Gowda,O V Loseva

doi:10.1134/s1070328417100013

Three-Dimensional Polymeric Thallium(I) Morpholinedithiocarbamate [Tl2{S2CN(CH2)4O}2] n and Its Capability of Binding Gold(III) from Solutions: Chemisorption Synthesis of a Heteronuclear Gold(III)–Thallium(III) Complex of the Ionic Type, ([Au{S2CN(CH2)4O}2][TlCl4]) n , the Role of Secondary Interactions Tl…O, Tl…S, and Au…S in the Supramolecular Self-Organization, 13C MAS NMR, and Thermal Behavior

O A Bredyuk, O N Antzutkin + Show 3 more

https://doi.org/10.1134/s1070328417100013

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Journal: Russian Journal of Coordination Chemistry	Publication Date: Sep 30, 2017
Citations: 6

Affiliation: Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences, University of Oulu, Luleå University of Technology

#13C MAS NMR #Supramolecular Self-Organization + Show 6 more

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Abstract

Crystalline polymeric thallium(I) morpholinedithiocarbamate [Tl2{S2CN(CH2)4O}2]n (I) and the heteronuclear ion–polymeric gold(III)–thalium(III) complex ([Au{S2CN(CH2)4O}2][TlCl4])n (II) are prepara ...

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