Abstract
Three novel coordination polymers (CPs), [Pb(bpbp)X2]n (X = Cl (1), Br (2), I (3), bpbp = 4,4′-bis(4-pyridyl)-biphenyl), were synthesized via solvothermal synthesis method. The three CPs are isostructural complexes exhibiting 2D inorganic-organic layer structures with (4, 4) topology which are constructed by Bpbp ligands connecting neutral [PbX2]n chains. The results of photoluminescence experiments and DFT calculations indicate that both the conjugated Bpbp ligands and halide anions show important roles in the emission process of CPs, and halide anions may slightly tune the structures and luminescence properties of CPs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
