Abstract
Stabilized phosphoranes were synthesized from the reaction between dimethyl acetylenedicarboxylate and amide derivatives in the presence of triphenylphosphine. Dimethylurea containing a phosphorus ylide underwent a smooth reaction in boiling toluene to produce hydantoin and oxo-oxazolidin containing stable phosphorus ylides in good yields. Phosphorus ylides derived from (PhO)3P were not stable and converted to diastereoisomeric phosphonates and phosphorimidate. The nature of the amide derivatives and type of trivalent phosphorus compounds, as well as solvents, determined the distribution of products.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Phosphorus, Sulfur, and Silicon and the Related Elements
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
