Abstract
Three new 7,7,8,8-tetracyanoquinodimethane (TCNQ) alkaline-earth metal complexes, namely {[M2(TCNQ)3(H2O)6]·TCNQ}n (M = Ca (1), Sr (2) and Ba (3)) have been synthesized by salt elimination reactions. X-ray crystallographic analysis reveals that complexes 1, 2 and 3 are isomorphic featuring a unique 3D structure. Cyclic and differential pulse voltammograms for complexes 1-3 show a reversible one-electron oxidation and a reversible one-electron reduction within the electrochemical window of CH3CN. Their electrochemical HOMO-LUMO gap and reversibility are examined.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
