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Abstract
Abstract Thionyl chloride is known to be a pyramidal structure as show below1) and has been known to be a good chlorinating reagent of aliphatic alcohols, amides, carbonylates, epoxides, oximes and sulfonic acids and various others.2) It reacts with phenols to afford phenolic diaryl sulfides3) A good example would be the reaction of a seconary alcohol with thionyl chloride, shown below,which has been known to proceed with a partial retention of configuration as shown below.
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