Abstract

As part of a programme to synthesize thione derivatives with pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]undecane moieties it was decided to sulfurize the monoacetal 6 of pentacyclo[5.4.0.0 2,6.0 3,10.0 5,9]undecane-8,11-dione 2 . Unexpectedly the diol 9 was isolated as the product.

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