Abstract

AbstractLawesson's reagent is one of the most common thionating reagents that has found use for several decades on a variety of carbonyl systems. Herein, we report the transformation of the 2‐λ5‐phosphaquinolin‐2‐one structure to its respective 2‐λ5‐phosphaquinolin‐2‐thione derivative. Solution‐state characterization of both P−OPh and P−Ph thio analogues, as well as solid‐state structures for the latter system, are reported.

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