Abstract
The decacarbonylditungstate dianion, readily generated from tungsten hexacarbonyl and sodium amalgam, undergoes a facile reaction with thioketones to give (thioketone)pentacarbonyltungsten(0) complexes in good to excellent yields. The latter complexes, and the molybdenum analog, were formed by treatment of a thione with the chloride-bridged tungsten and molybdenum tricarbonylmetalates, [M 2(CO) 6Cl 3] 3− (M = W, Mo).
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