Thiocyanate-selective membrane electrode based on cobalt(III) Schiff base as a charge carrier

Abstract

A highly selective polyvinylchloride (PVC) membrane electrode based on Schiff base complex i.e. [Cobalt (Salpen) (PBu3)] ClO4 · H2O (Salpen = bis(salycilaldehyde)propylene diamine) is reported as new carrier for thiocyanate selective electrode by incorporating the membrane ingredients on the surface of graphite electrodes. The proposed electrode possesses a very wide Nernestian linear range to thiocyanate from 1.0 × 10−6 to 1.0 × 10−1 M with slope of −59.05 ± 0.91 mV per decade of thiocyanate concentration, very low detection limit (8.0 × 10−7 M) and good thiocyanate selectivity over the wide variety of other anions. Fast and stable response, good reproducibility, long-term stability, applicability over a wide pH range (2.8–9.8) are advantages of the reported electrode. The sensor has a response time of <5 s and can be used for at least 14 weeks without any considerable change in respective potential response. The proposed electrode was used for the determination of thiocyanate in saliva, wastewater and human urine with satisfactory results and good agreement with colorimetric as reference method.