Thin-walled porous carbon tile-packed paper for high-rate Zn-ion capacitor cathode

Abstract

Lengthened ion pathway in porous carbon cathode, especially under high mass loading and packing state, severely impeded the ion transport, thus leading to a far unsatisfactory energy/power out of Zn//C capacitors. Here, we report a novel kapok-derived quasi-2D thin-walled porous carbon tile (CT) with proper curvature and rich doping used as stacked bricks. Together with high conductivity single-walled carbon nanotubes, a porous yet relatively packed self-standing carbon cathode was constructed, which features a hierarchical ion path including short ion pathways inside thin-walled porous CTs and adequate channels “highways” caused by rational sub-micron interlayer spacing, thus leading to an excellent combination of rate and gravimetric/volumetric/areal performance at practical mass loading (12 mg cm −2 ). • A porous thin-walled layered carbon tile with proper curvature was prepared as bricks. • Porous yet packed cathode feathers hierarchical paths for fast ion/charge transfer. • High rate and gravimetric/volumetric capacity remain in high loading cathode. • The areal capacity increases linearly with the mass loading of cathode. Long ion pathway inside large-sized carbon particle or stacked 2D assembly greatly limit the electrochemical performance of practical carbon cathode (>10 mg cm −2 ) in Zn//C capacitors. Highly porous activated carbon and holy graphene can alleviate such ion-transport issue, but usually suffer from a far lower packing density and severe restacking, respectively. Herein, a kapok-derived quasi-2D thin-walled microporous carbon tile (CT) with optimized curvature and rich doping was developed and used as bricks. Assisted with single-walled carbon nanotubes (SWNTs), a porous yet relatively packed paper cathode was constructed. The unique doped thin wall (∼700 nm) can effectively shorten the ion-penetration pathways from electrolyte deep into pore structure inside CTs, and thus enlarge ion-accessible surface areas. Combined with rational sub-micron interlayer spacing among proper-curved CTs and bridged-like SWNTs, the continuous ion/charge transport “highways” are fabricated. As a result, such self-standing carbon cathode delivers outstanding rate and gravimetric/areal performance (114 mAh g −1 /1.37 mAh cm −2 ) without sacrificing volumetric capacity even at high mass loading (12 mg cm −2 ).