Abstract

We have used spectroscopic ellipsometry in the photon energy range 1.5–2.5 eV to determine the dielectric function of thin films (3–30nm) of undoped poly(3-hexylthiophene) prepared with a spinning technique on gold substrates. We have observed characteristic absorption peaks in the energy range 2–2.5 eV. By means of second derivative lineshape fitting, we demonstrate that it is possible to quantitatively extract values on model parameters like peak energies, linewidths and oscillator strengths. We also show how light-induced degradation changes the polymer as reflected in the dielectric response of the polymer.

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