Thin film yttria-stabilized zirconia electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs) by chemical solution deposition

Abstract

Abstract A 500 nm thick thin film YSZ (yttria-stabilized zirconia) electrolyte was successfully fabricated on a conventionally processed anode substrate by spin coating of chemical solution containing slow-sintering YSZ nanoparticles with the particle size of 20 nm and subsequent sintering at 1100 °C. Incorporation of YSZ nanoparticles was effective for suppressing the differential densification of ultrafine precursor powder by mitigating the prevailing bi-axial constraining stress of the rigid substrate with numerous local multi-axial stress fields around them. In particular, adding 5 vol% YSZ nanoparticles resulted in a dense and uniform thin film electrolyte with narrow grain size distribution, and fine residual pores in isolated state. The thin film YSZ electrolyte placed on a rigid anode substrate with the GDC (gadolinia-doped ceria) and LSC (La0.6Sr0.4CoO3−δ) layers deposited by PLD (pulsed laser deposition) processes revealed that it had fairly good gas tightness relevant to a SOFC (solid oxide fuel cell) electrolyte and maintained its structural integrity during fabrication and operation processes. In fact, the open circuit voltage was 1.07 V and maximum power density was 425 mW/cm2 at 600 °C, which demonstrates that the chemical solution route can be a viable means for reducing electrolyte thickness for low- to intermediate-temperature SOFCs.