Abstract
Thin BN films (100–250 nm) have been deposited on Si(100) substrates in a double-ion-beam sputtering system from a h-BN target. The films have been characterized by FT-IR spectroscopy and spectroscopic phase-modulated ellipsometry as a function of the deposition and irradiation parameters. Assistance with Ar + ions result in boron rich films with refraction indexes above 2 or even higher as the deposited energy of the assisting ions increases. N 2 +-bombardment causes stoichiometric and even nitrogen-rich BN films characterized by refraction indexes around 1.85. The stability of the films is enhanced when the deposited energy of the N 2 + ions is above 30 eV/atom and/or the deposition is performed on substrates at temperatures above 100°C.
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