Abstract

Thin films of thicknesses 250–339 nm of 3, 4-ethylenedioxythiophene (EDOT) have been prepared onto glass substrates at room temperature under AC (50 Hz) power using plasma polymerization (PP) technique. Field emission scanning electron microscopy images exhibit immaculate and pinhole-free surface morphology of the PPEDOT. Fourier transform infrared spectroscopy analysis represents that the chemical compositions of the as-deposited PPEDOT films are different from that of EDOT indicating some structural rearrangement. The band gap energy of the PPEDOT thin films decreases from 3.65 eV to 3.75 eV with the increase of film thickness. Urbach energy, steepness parameter, extinction coefficient, refractive index, and other optical parameters were also studied to elucidate the suitability of these films for use in various optoelectronic devices.

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