Abstract

A series of (Y1-xErx)TaO4 ceramics (x=0/6, 1/6, 2/6, 3/6, 4/6, 5/6, 6/6) were prepared using powders synthesized by the reverse co-precipitation technique. Investigations were conducted into the phase compositions, microstructure, and thermophysical characteristics. In contrast to yttria-stabilized zirconia (YSZ) ceramics, (Y1-xErx)TaO4 ceramics demonstrate reduced thermal conductivity and Young's modulus, along with greater coefficient of thermal expansions (CTEs). The impact of Er and Y elements on separation interferes with the parabolic relationship between thermal conduction and the composition of (Y1-xErx)TaO4 ceramics, modifying their thermal diffusion and conductivity patterns. Furthermore, the performance of (Y1-xErx)TaO4 ceramics was optimized by adjusting the ratio of Er/Y, from which (Y1-xErx)TaO4 ceramics exhibited lower thermal conductivity (1.38∼1.72 W·m-1·K-1 @ 800 °C), higher CTEs (9.24×10-6∼10.9×10-6 K-1 @ 1000 °C) and more excellent mechanical properties comparable to YSZ. Herein, (Y1-xErx)TaO4 ceramics show great potential for thermal barrier coating applications.

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