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Abstract
The anionic binary Ionic liquids; TMPAFSAxTFSA1-x were prepared as mixture of TMPATFSA and TMPAFSA. From the results of DSC analysis, the binary system showed the simple binary eutectic phase diagram and the eutectic point was found at the composition point of x = 0.33. In this system, each anion vibrated independently and showed isomerization equilibria displacement with temperature change. It was suggested that the equilibria displacements affected to the liquid structure and cis-trans isomerization of each anion played an important role in the solidification of TMPAFSAxTFSA1-x.
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