Thermophysical and Radiative Properties of Conductive Biopolymer Composite

Abstract

Usual plate solar collectors, based on a metal absorber (Cu, Al) selectively coated are technologically very sophisticated, expensive to produce and they are great consumer of fossil raw material. Polymeric materials are considered as a promising alternative for many interesting properties; easy moldability, corrosion resistance, they also offer a significant cost-reduction for solar thermal collectors, and a mass production may thus benefit to a broader utilization of solar energy. Most drawbacks of polymers are their low thermal properties; essentially thermal conductivity coefficient may strongly affect the solar absorber efficiency and deteriorate the collector performance. Polymers used in solar collectors are mainly petroleum-derivative product and mass use of them is not a response to environmental concern. That is why the laboratory chose to explore the potentialities of bio-polymers for the production of absorbers. This group of material presents the same properties as ordinary polymers. It is on the other hand possible to modify the thermal properties of the basic matrix by the addition of loads, such as carbon black, graphite or carbon nanotubes. The thermal performance of a solar collector is closely related to the thermal properties of the absorber. Within this framework, many measurements are necessary, more particularly the conductivity, but also emissivity and absorptivity to solar radiation. The aim of this paper is to study the thermal properties of the PLA bio-polymer charged of exfoliated graphite and/or CNT. Thereafter, the total hemispherical absorptivity, an estimation of the total hemispherical emissivity and the thermal conductivity coefficient were measured for different load rates, we will conclude on the interest and the potentialities of tested materials.