Abstract
Kinetic measurements by 1H NMR spectroscopy and chemically induced dynamic nuclear polarization (CIDNP) effects were used to study thermolysis of solutions of acetyl propionyl peroxide in methanol-d4. It is found that the thermolysis may occur both by radical and by nonradical mechanisms. A scheme of the thermolysis is proposed. Parameters of the Arrhenius equation for the rate constants of the decomposition of the peroxide and the decarboxylation of acyloxyl radicals are obtained.
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