Abstract
Thermolysis of N-phenyl-O-phenylthiocarbamate (POPTC), N-phenyl-O-benzylthiocarbamate (POBTC), and N-phenyl-S-phenylthiocarbamate (PSPTC) by reflux for 15 hr at 220–230 °C affords degradation products assumed to be formed by homolysis at different sites furnishing free radicals that undergo subsequent reactions involving H-abstraction, dimerization, disproportionation and/or fragmentation to give the identitied products. Similar results are also obtained on photolysis of such thiocarbamate derivatives.
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