Abstract

SrSO4 nanoparticles doped with different concentrations of Eu were synthesised by using co-precipitation method and annealed at 500 °C, 700 °C and 900 °C respectively. The prepared SrSO4:Eu nanophosphors shows highly crystalline orthorhombic structure with crystallite size of about 30 nm as observed from the X-ray diffraction (XRD) pattern. TEM (Transmission Electron Microscopy) analysis confirms the particle size to be around 40 nm for the synthesised nanophosphors. Energy Dispersive X-ray (EDX) spectrum showed the presence of only Eu dopant without any other impurity into the SrSO4 sample. The thermoluminescence (TL) glow curve of 1 Gy of gamma ray irradiated SrSO4:Eu measured at heating rates 1 K/s has a well-defined single peak at around 468 K. The TL kinetic parameters for the synthesised nanoparticles evaluated using initial rise method, peak shape method, Booth method and deconvolution method were all in agreement and found to be activation energy (E), order of kinetics (b) and frequency factors (s).

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