Thermoluminescence glow curve analysis and trap parameters calculation of UV-induced La2Zr2O7 phosphor doped with gadolinium

Abstract

Thermoluminescence (TL) glow curve analysis and calculation of trap parameters are reported for gadolinium (Gd3+)-doped La2Zr2O7 (LZO) phosphor. Phosphors were prepared by modified solid-state reaction method with varying concentration of Gd3+ (0.1–2.5 mol%) including proper calcination and sintering temperature. Structural analysis of prepared phosphor for optimized TL concentration was recorded by X-ray diffraction analysis technique. Morphology was analyzed by scanning electron microscopic technique. The UV ray induced to the phosphor and effect of dose response recorded for variable dose rates of UV and TL glow curve were observed. The experimental and theoretical comparison was done by computerized glow curve deconvolution technique which determines the trap parameters such as trap depth, order of kinetics, and frequency factor for optimized concentration of dopant. The trap parameters and trap model are discussed in detail.