Thermogravimetric-infrared analysis and performance optimization of co-pyrolysis of oily sludge and rice husks

Abstract

In this paper, thermogravimetric-infrared spectroscopy was used to analyze co-pyrolysis of oily sludge (OS) from oil penetration and rice husks (RH) at various ratios (1:0; 3:1; 1:1; 1:3; 0:1), obtaining pyrolysis weight-loss behaviors, the laws of mutual synergy, and gas volatilization characteristics. The Coats-redfern and response surface method were employed to analyze kinetics and optimize pyrolysis, respectively. The Ti, Tmax, and Tf increase as the heating rate increases, and the weight loss increases in the second stage. With the increase of the proportion of RH, the Ti and Tmax of the mixture increase, while the Tf and residual content decrease. The co-pyrolysis of the OS and RH has synergistic effects. The addition of RH is beneficial to reduce the E of OS pyrolysis. The mixing ratio affects the strength of small-molecular-gases volatilization. When the RH ratio is 58.9% at 10K/min, the minimum predicted E and residual amount of co-pyrolysis are 58.602 kJ/mol and 42.6%, respectively.