Thermogelling Properties of Triblock Copolymers in the Presence of Hydrophilic Fe3O4 Nanoparticles and Surfactants

Abstract

We investigate the supramolecular structure formed by thermogelation of a triblock polymer in the presence of nanoparticles and surfactant using rheometry and small-angle X-ray scattering (SAXS). The triblock copolymer, nanoparticle, and surfactant used in this study are poly(oxyethylene-oxypropylene-oxyethylene), Pluronic F108, Fe(3)O(4) nanoparticles, and sodium dodecyl surfactant, respectively. Addition of 1-5 wt % of Fe(3)O(4) nanoparticle, of average particle size ~10 nm, in a weak template of F108 (15 wt %) shows a decrease in the onset of gelation temperature and dramatic alteration in the viscoelastic moduli. The nanocomposite samples show a linear viscoelastic regime up to 5% strain. The SAXS measurement shows that the intermicellar spacing of the supramolecular structure of pure F108 is ~16.5 nm, and the supramolecular structure is destroyed when nanoparticles and surfactants are incorporated in it. Further, the addition of anionic surfactant to nanocomposites leads to a dramatic reduction in the viscoelastic properties due to strong electrostatic barrier imparted by the surfactant headgroup that prevents the formation of hexagonally ordered micelles. Our results show that the thermogelation is due to the clustering of nanoparticles into a fractal network rather than a close-packed F108 micelles, in agreement with the recent findings in Pluronic F127-laponite systems.