Thermoformable and transparent one-component nanocomposites based on surface grafted cellulose nanofiber

Abstract

One-component nanocomposites based on poly(methyl methacrylate)(PMMA) and polystyrene (PS) grafted cellulose nanofiber (CNF) with high polymer graft percentage were fabricated. At relative ambient conditions, less active vinyl monomer, MMA, and styrene were grafted from CNF via surface-initiated Cu(0)-mediated reversible deactivation radical polymerizations (RDRP), and PMMA/PS grafted CNFs could reach a graft percentage as high as 7550 % and 3530 %, respectively. The one-component composite films were manufactured by simple hot-pressing subsequentially. Optical transparency, thermal stability, and glass transition temperature of one-component nanocomposites were enhanced dramatically in contrast with the bicomponent nanocomposite. The uniform fracture surface confirmed the uniform dispersity by morphological observation. Mechanical tests indicated that break elongation and tensile strength ascended notably, and tensile modulus slightly descended as the graft percentage increased for PS and PMMA grafted CNF one-component composite. It was concluded that for glassy graft chains, obtaining one-component nanocomposites with high enough graft chain length was essential to achieve moderated mechanical performance without compromising optical properties and thermal manufacturing ability.