Abstract

I-doped Bi2Te2.85Se0.15 solid solutions were prepared by encapsulated melting and hot pressing. The electrical conductivity and the electronic thermal conductivity were increased due to an increase in the carrier concentration with increasing I content, but the lattice thermal conductivity was reduced because I atoms affected the lattice disorder, with I atoms acting as phonon scattering centers. The undoped solid solution showed a carrier concentration of 7.37 × 1019 cm−3, a power factor of 2.1 mWm−1K−2 and a dimensionless figure of merit (ZT) of 0.56 at 323 K. The ZT value was improved due to an increase in the power factor by I doping, and the maximum ZT was obtained as 0.90 at 423 K for Bi2Te2.85Se0.15:I0.005.

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