Abstract
Single phase Ca1−xSrxRuO3 (x=0–1.0) powders were synthesized by a solid-state reaction and compacted by spark plasma sintering. The a-length of the lattice parameter showed a slight minimum around x=0.6, whereas the b-length, c-length and the unit cell volume increased continuously with increasing x from 0 to 1.0, indicating a solid solution in the whole range. The relative density of Ca1−xSrxRuO3 compacted bodies increased from 75 to 95% with increasing x from 0 to 1.0. The electrical conductivity (σ) at x=0.1–0.9 was higher than those of the end members (CaRuO3 and SrRuO3) except for that at x=0.5, and showed metallic conduction at all compositions. The Seebeck coefficient (S) was 30–40μVK−1, almost independent of composition and temperature. The thermal conductivity (κ) was 2–3Wm−1K−1 at room temperature and increased with increasing temperature. The κ showed the lowest values at x=0.2 in the whole temperature range. The dimensionless figure-of-merit (ZT) at x=0.1–0.9 was higher than those of the end members. The highest ZT was 0.07 at x=0.2 and 600K.
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