Abstract

The thermal variation of the electrical resistivity and thermoelectric power of Bi1.6Pb0.4Sr2Ca2Cu3O10 + δ pellets subjected to various degrees of deoxygenation is reported. The temperature dependence of the electrical resistivities of deoxygenated samples displays gradual transformation from metallic-like to semiconductor-like features in the normal state. All the samples however, show superconducting transition, but increasing deoxygenation depresses TC0 from 102 to 45 K. Gross features of the temperature variation of thermoelectric power observed in properly oxygenated (Bi, Pb)-2223 cuprates are retained in all the deoxygenated samples. Our results on electrical resistivity and thermoelectric power in the normal state have been found to be consistent with a two-band model.

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