Abstract

Fundamental studies on the thermoelectricity have been mainly done in the pseudo binary systems of Mg2Si – Mg2Ge – Mg2Sn. In recent years, their thermoelectricity is revisited because of light-weight, low initial const and short turning back time in addition to high potential in figureof- merit for ZT approaching to unity or more. Conventional melting and solidification, or, normal PM routes fail in precise, wide-range control of chemical composition and microstructure control. New PM route via bulk mechanical alloying is developed to fabricate the solid solution semiconductive materials with Mg2Si1-xGex and Mg2Si1-ySny for 0

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