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Abstract
The molten binary mixture ZnCl2-NaCl was studied by means of emf measurements on galvanic cells. In these cells Pyrex glass functions as a sodium inditor electrode. The excess free enthalpy of mixing at 600°C has been calculated from the emf mesurements. The ZnCl2-NaCl mixture shows a stronger negative deviation from ideal mixing behaviour than the corresponding lead chloride and cadmuim chloride mixtures.
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