Abstract
AbstractThe adsorption of zinc chloride on calcite, dolomite and Casubstituted magnesite crystals from aqueous solution is treated theoretically; and a standard adsorption process is thereby rigorously defined. The thermodynamic characteristics Δ F0θ, Δ H0θ and Δ S0θ are determined for this process by means of adsorption isotherm data at various temperatures with crystals of measured surface area.It is found that about 10% of the adsorption sites probably available on calcite are occupied by zinc when the equilibrium Zn++aq concentration is 0.90 × 10‐6 M at 25.1° C. The Ca‐magnesite shows a somewhat greater affinity for zinc ion than calcite, while dolomite is intermediate. The temperature coefficients of Δ F0θ are opposite in sign for calcite and the other two minerals. The resulting endothermic heats of adsorption of Zn++aq on the dolomite and the Ca‐magnesite (Δ H0θ = 8.21 ± 2.4 and 22.7 ± 5.9 kcal/mole at about 27° C, respectively), as well as the corresponding very large positive entropies of adsorption (Δ S0θ = 56 ± 8 and 106 ± 20 cal/deg × mole at about 27° C, respectively) indicate that Zn++aq is dehydrated when adsorbed by these two minerals. The known compatability of Zn++ with the MgCO3 crystal lattice is suggested as the reason for the strong interaction of this ion with the dolomite and Ca‐magnesite, relative to calcite.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
