Abstract
The mass spectra of vapours over { xCdCl 2 + (1 − x)CdBr 2}(s) have been measured at the temperature 600 K. The ions Cd +, CdCl +, CdBr +, CdCl 2 +, CdBr 2 +, and CdClBr + have been found. The excess molar Gibbs free energy has been determined: G E m(600 K) (J · mol −1) = −(7100 ± 290)x(1−) The mass spectrum of CdClBr(g) and the equilibrium constant of the reaction of formation of CdClBr(g) at 600 K have been calculated.
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