Abstract
The mass spectrum over {xCdBr2 + (1−x)CdI2}(s) measured at the temperature 550 K exhibits the ions Cd+, CdBr+, CdI+, CdBr2+, CdI2+, and CdBrI+. The excess molar Gibbs free energy of the solid mixture has been obtained: GEm(550 K)(J·mol−1) = x(1−x){(−306±114)+(−1404±172)(2x−1)}The mass spectrum of CdBrI(s) and the standard equilibrium constant of the reaction of formation of CdBrI(g) from 12CdBr2(g) and 12CdI2(g) at 550 K have been calculated.
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